532 Publications (Page 1 of 22)
2021
Back donation, intramolecular electron transfer and N–O bond scission targeting nitrogen oxyanion reduction: how can a metal complex assist?
Beagan, Daniel M⋅Cabelof, Alyssa C and Caulton, Kenneth G
Dalton Transactions, vol. 50, (no. 6), pp. 2149-2157, 2021. | Journal Article
2020
A Dimeric Chromium(II) Pincer as an Electron Shuttle for N=N Bond Scission
Labrum, Nicholas S⋅Cabelof, Alyssa C and Caulton, Kenneth G
Chemistry – A European Journal, 2020-05-19. | Journal Article
A reagent for heteroatom borylation, including iron mediated reductive deoxygenation of nitrate yielding a dinitrosyl complex
Beagan, Daniel M⋅Carta, Veronica and Caulton, Kenneth G
Dalton transactions (Cambridge, England : 2003), vol. 49, (no. 5), pp. 1687, 2020-Feb-07. | Journal Article
A reagent for heteroatom borylation, including iron mediated reductive deoxygenation of nitrate yielding a dinitrosyl complexElectronic supplementary information (ESI) available: Spectral data, XRD information, computational data. CCDC 1951267, 1951269 and 1951270. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/d0dt00077a
Beagan, Daniel M⋅Carta, Veronica and Caulton, Kenneth G
(no. 5), pp. 1687, 20200205. | Journal Article
The Influence of Nucleophilic and Redox Pincer Character, and Alkali Metals, on Capture of Oxygen Substrates: The Case of Chromium(II)
Labrum, Nicholas S⋅Curtin, Gregory M⋅Jakubikova, Elena and Caulton, Kenneth G
Chemistry (Weinheim an der Bergstrasse, Germany), 2020-Mar-18. | Journal Article
Unusual Dinitrogen Binding and Electron Storage in Dinuclear Iron ComplexesSorsche, Dieter⋅Sorsche, Dieter Ulrich⋅Miehlich, Matthias⋅Miehlich, Matthias E⋅Searles, Keith⋅Searles, Keith⋅Gouget, Guillaume⋅Gouget, Guillaume⋅Zolnhofer, Eva M⋅Zolnhofer, Eva M.⋅Fortier, Skye⋅Fortier, Skye⋅Chen, Chun-Hsing⋅Chen, Chun-Hsing⋅Gau, Michael⋅Gau, Michael R.⋅Carroll, Patrick J.⋅Carroll, Patrick J⋅Murray, Christopher B⋅Murray, Christopher B.⋅Caulton, Kenneth G⋅Caulton, Kenneth G.⋅Khusniyarov, Marat M.⋅Khusniyarov, Marat M⋅Meyer, Karsten⋅Meyer, Karsten⋅Mindiola, Daniel J and Mindiola, Daniel J.Journal of the American Chemical Society, vol. 142, (no. 18), pp. 8159, 2020-May-06.
| Journal Article
2019
A bis-Pyrazolate Pincer on Reduced Cr Deoxygenates CO 2 : Selective Capture of the Derived Oxide by Cr II
Labrum, Nicholas S⋅Chen, Chun-Hsing and Caulton, Kenneth G
Chemistry (Weinheim an der Bergstrasse, Germany), vol. 25, (no. 33), pp. 7940, 2019-Jun-12. | Journal Article
A new face for bispyridine: Incompatible geometric preferences dictates unprecedented pincer ligand connectivity
Labrum, Nicholas⋅Chen, Chun-Hsing and Caulton, Kenneth
Inorganica Chimica Acta, vol. 485, pp. 54, 20190124. | Journal Article
[Cr(pincer2−)]2 as an electron shuttle for reductively promoted hydrazine disproportionation
Labrum, Nicholas S and Caulton, Kenneth G
Dalton Transactions, vol. 48, (no. 31), pp. 11646, 2019-00-00. | Journal Article
[Cr(pincer2−)]2 as an electron shuttle for reductively promoted hydrazine disproportionationElectronic supplementary information (ESI) available: Synthetic details, crystallographic data, and XPS data are included. CCDC 1906015. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9dt02300c
Labrum, Nicholas S and Caulton, Kenneth G
(no. 31), pp. 11646, 20190806. | Journal Article
Di- and trivalent chromium bispyridine pincer complexes with good leaving groups
Labrum, Nicholas⋅Labrum, Nicholas⋅Seo, Junghee⋅Seo, Junghee⋅Chen, Chun-Hsing⋅Chen, Chun-Hsing⋅Pink, Maren⋅Pink, Maren⋅Beagan, Daniel⋅Beagan, Daniel⋅Caulton, Kenneth and Caulton, Kenneth
Inorganica Chimica Acta, vol. 486, pp. 483, 20190224. | Journal Article
Gauging the Redox Non‐Innocence of a Highly Pi‐Acidic Bis‐Tetrazine Pincer Ligand
Cook, Brian J⋅Lord, Richard L⋅Chen, Chun‐Hsing and Caulton, Kenneth G
European Journal of Inorganic Chemistry, vol. 2019, (no. 20), pp. 2542, June 2, 2019. | Journal Article
Multi-electron Reduction Capacity and Multiple Binding Pockets in Metal–Organic Redox Assembly at SurfacesMorris, Tobias⋅Morris, Tobias⋅Morris, Tobias⋅Huerfano, I.⋅Huerfano, I.⋅Huerfano, I.⋅Wang, Miao⋅Wang, Miao⋅Wang, Miao⋅Wisman, David⋅Wisman, David⋅Wisman, David⋅Cabelof, Alyssa⋅Cabelof, Alyssa⋅Cabelof, Alyssa⋅Din, Naseem⋅Din, Naseem⋅Din, Naseem⋅Tempas, Christopher⋅Tempas, Christopher⋅Tempas, Christopher⋅Le, Duy⋅Le, Duy⋅Le, Duy⋅Polezhaev, Alexander⋅Polezhaev, Alexander⋅Polezhaev, Alexander⋅Rahman, Talat⋅Rahman, Talat⋅Rahman, Talat⋅Caulton, Kenneth⋅Caulton, Kenneth⋅Caulton, Kenneth⋅Tait, Steven⋅Tait, Steven and Tait, StevenChemistry - A European Journal, vol. 25, (no. 21), 2019-03-18.
| Journal Article
Reactivity of an Unusual Divalent Chromium Aggregate Supported by a Multifunctional Bis(pyrazolate) Pincer Ligand
Labrum, Nicholas S⋅Labrum, Nicholas S⋅Pink, Maren⋅Pink, Maren⋅Chen, Chun-Hsing⋅Chen, Chun-Hsing⋅Caulton, Kenneth G and Caulton, Kenneth G
European Journal of Inorganic Chemistry, vol. 2019, (no. 14), pp. 1940, 2019-04-16. | Journal Article
Reductive Silylation Using a Bis‐silylated Diaza‐2,5‐cyclohexadiene
Beagan, Daniel M⋅Beagan, Daniel M⋅Huerfano, I. J⋅Huerfano, I. J⋅Polezhaev, Alexander V⋅Polezhaev, Alexander V⋅Caulton, Kenneth G and Caulton, Kenneth G
Chemistry – A European Journal, vol. 25, (no. 34), pp. 8111, June 18, 2019. | Journal Article
Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation
Seo, Junghee⋅Cabelof, Alyssa⋅Chen, Chun-Hsing and Caulton, Kenneth
Chemical Science, vol. 10, (no. 2), 2019-01-01. | Journal Article
Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylationElectronic supplementary information (ESI) available: NMR, MS (ESI, APCI), FT-IR, EPR, XPS, CV, DFT, and crystal structure data for H2LCr(NO3)2(NO). CCDC 1848665. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc02979b
Seo, Junghee⋅Cabelof, Alyssa C⋅Chen, Chun-Hsing and Caulton, Kenneth G
(no. 2), pp. 479, 20190102. | Journal Article
2018
A Multifunctional Pincer Ligand for Cobalt-Promoted Oxidation by N 2 O
Cook, Brian J⋅Chen, Chun-Hsing and Caulton, Kenneth G
Chemistry (Weinheim an der Bergstrasse, Germany), 2018-Feb-13. | Journal Article
A Multifunctional Pincer Ligand for Cobalt-Promoted Oxidation by N2 O
Cook, Brian J⋅Chen, Chun-Hsing and Caulton, Kenneth G
Chemistry - A European Journal, vol. 24, (no. 22), pp. 5966, 2018-04-17. | Journal Article
A multimetal-ligand cooperative approach to CO.sub.2 activation
Cook, Brian⋅Cook, Brian⋅Cook, Brian⋅Polezhaev, Alexander⋅Polezhaev, Alexander⋅Polezhaev, Alexander⋅Chen, Chun-Hsing⋅Chen, Chun-Hsing⋅Chen, Chun-Hsing⋅Pink, Maren⋅Pink, Maren⋅Pink, Maren⋅Caulton, Kenneth⋅Caulton, Kenneth and Caulton, Kenneth
Inorganica Chimica Acta, vol. 483, pp. 510, 20181101. | Journal Article
A new access route to dimetal sandwich complexes, including a radical anion
Labrum, Nicholas S⋅Losovyj, Yaroslav and Caulton, Kenneth G
Chemical communications (Cambridge, England), vol. 54, (no. 87), pp. 12399, 2018-Oct-30. | Journal Article
A new access route to dimetal sandwich complexes, including a radical anionElectronic supplementary information (ESI) available: Synthetic details, crystallographic data, and XPS data are included. CCDC 1846355. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8cc05204b
Labrum, Nicholas S⋅Losovyj, Yaroslav and Caulton, Kenneth G
(no. 87), pp. 12399, 20181030. | Journal Article
A PNNH Pincer Ligand Allows Access to Monovalent IronPolezhaev, Alexander V⋅Polezhaev, A.V.⋅Polezhaev, Alexander V⋅Liss, C.J.⋅Liss, Cameron J⋅Liss, Cameron J⋅Telser, J.⋅Telser, Joshua⋅Telser, Joshua⋅Chen, C.-H.⋅Chen, Chun‐Hsing⋅Chen, Chun‐Hsing⋅Caulton, Kenneth G⋅Caulton, K.G. and Caulton, Kenneth GChemistry – A European Journal, vol. 24, (no. 6), pp. 1341, January 26, 2018.
| Journal Article
A substituent-tolerant synthetic approach to N/P-"loaded" heteroarenes
Polezhaev, Alexander V⋅Polezhaev, Alexander V⋅Beagan, Daniel M⋅Beagan, Daniel M⋅Cabelof, Alyssa C⋅Cabelof, Alyssa C⋅Chen, Chun-Hsing⋅Chen, Chun-Hsing⋅Caulton, Kenneth G and Caulton, Kenneth G
Dalton transactions (Cambridge, England : 2003), vol. 47, (no. 17), pp. 5942, 2018-May-01. | Journal Article
Dehydrohalogenation of proton responsive complexes: versatile aggregation via pyrazolate pincer ligand arms
Cook, Brian J⋅Cook, Brian J⋅Chen, Chun-Hsing⋅Chen, Chun-Hsing⋅Pink, Maren⋅Pink, Maren⋅Caulton, Kenneth G and Caulton, Kenneth G
Dalton transactions (Cambridge, England : 2003), vol. 47, (no. 6), pp. 2060, 2018-Feb-06. | Journal Article